An explanation of reported participation of hydrated electrons as intermediates in electrochemical reduction reactions
作者:
John R. Duncan,
Graham A. Wright,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1978)
卷期:
Volume 56,
issue 1
页码: 17-23
ISSN:0008-4042
年代: 1978
DOI:10.1139/v78-003
出版商: NRC Research Press
数据来源: NRC
摘要:
Suggestions that e−(aq)is involved as a reactant in reduction reactions at metal electrodes are examined. It is shown that an experimental test of the participation of e−(aq)can be devised. The results of this test show that the conventional theory, involving electron transfer directly from the electrode to the species being reduced, provides a better explanation of the reduction process in aqueous solution.
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