首页   按字顺浏览 期刊浏览 卷期浏览 Fast current limitation by conducting polymer composites
Fast current limitation by conducting polymer composites

 

作者: R. Stru¨mpler,   G. Maidorn,   J. Rhyner,  

 

期刊: Journal of Applied Physics  (AIP Available online 1997)
卷期: Volume 81, issue 10  

页码: 6786-6794

 

ISSN:0021-8979

 

年代: 1997

 

DOI:10.1063/1.365222

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The transition of materials from low resistivity to comparatively high resistivity can be utilized for current limitation, enabling permanent fuses that do not have to be replaced after an overload or short-circuit operation. An interesting class of materials for this purpose are particulate filled polymer composites with a strong positive temperature coefficient (PTC) of resistivity. If an applied current becomes too high, the PTC element is heated to its critical temperature and trips from the conducting into the insulating state. The dynamic heating of the composite upon current flow is described by a one-dimensional model. It is predicted that the heating of a composite depends on the size of the filler particles. Smaller filler particles should allow a faster heating and, hence, a better limitation of the current. Experimental verification is performed using composite ofTiB2particles in a polyethylene matrix. CommercialTiB2powders with different particle-size distributions between 1 and 200 &mgr;m were used. The specific resistivity of the composites is small, in the range of 0.01–0.02 &OHgr; cm. Around the melting temperature of the polymer, the resistivity increases within only 20 °C by seven orders of magnitude. In order to verify the expected dependence of the switching dynamic on the filler particle size, the tested elements had comparable electrical characteristics. Samples were prepared having, to a certain degree, the same specific resistivity, cross section, and total resistance. Free parameters were the length, and for some samples, the filler content. Short-circuit experiments show that for decreasing particle size the time until the material trips into the high-resistive state becomes shorter. The best current limitation occurs for composites containing particles in the range of 1–45 &mgr;m. Current limitation starts already after 150 &mgr;s, and a current density of up to10 kA/cm2can be switched off within a further 200 &mgr;s. The experiments are in excellent agreement with the predictions from theory. Due to the low resistance in the cold state and the very fast limitation of electrical currents, PTC elements based on conducting polymers can be highly attractive for power applications. ©1997 American Institute of Physics.

 

点击下载:  PDF (375KB)



返 回