Steric effects in the electronic spectra of substituted benzophenones. I: Symmetrically substituted methyl‐benzophenones
作者:
R. F. Rekker,
W. Th. Nauta,
期刊:
Recueil des Travaux Chimiques des Pays‐Bas
(WILEY Available online 1954)
卷期:
Volume 73,
issue 12
页码: 969-979
ISSN:0165-0513
年代: 1954
DOI:10.1002/recl.19540731202
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractThe ultraviolet absorption spectra of benzophenones show well‐defined steric effects arising fromortho‐substitutions.In this paper the experimental data are given for a series of 12 methylsubstituted ketones, including benzophenone.From these data the oscillator strengthsfwere calculated for the C‐bands; mutual comparison of thesef‐values gives and idea of the magnitude of the steric effects caused byortho‐substituted meth
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