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Kinetische Untersuchungen zur Pyrolyse von Mono‐n‐alkyl‐cyclohexanen

 

作者: W. Zychlinski,   G. Bach,   B. Glauch,   G. Zimmermann,  

 

期刊: Journal für Praktische Chemie  (WILEY Available online 1983)
卷期: Volume 325, issue 1  

页码: 66-74

 

ISSN:0021-8383

 

年代: 1983

 

DOI:10.1002/prac.19833250109

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

Kinetic Investigations of the Pyrolysis of Mono‐n‐alkyl‐cyclohexanesThe thermal decomposition of cyclohexane and six mono‐n‐alkylcyclohexanes was studied kinetically in a metallic laboratory tubular reactor at 650 to 850°C and atmospheric pressure.Kinetic parameters were found to be a function of length of the alkylic side chain. A comparison with analogous parameters of n‐paraffins and the unsubstituted cyclohexane allowed the conclusion that CC‐scission in the alkylic chain is the initial reaction in pyrolysis of n‐alkylcyclohexanes followed by radical attacks to all CH‐bonds

 

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