Kinetische Untersuchungen zur Pyrolyse von Mono‐n‐alkyl‐cyclohexanen
作者:
W. Zychlinski,
G. Bach,
B. Glauch,
G. Zimmermann,
期刊:
Journal für Praktische Chemie
(WILEY Available online 1983)
卷期:
Volume 325,
issue 1
页码: 66-74
ISSN:0021-8383
年代: 1983
DOI:10.1002/prac.19833250109
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Kinetic Investigations of the Pyrolysis of Mono‐n‐alkyl‐cyclohexanesThe thermal decomposition of cyclohexane and six mono‐n‐alkylcyclohexanes was studied kinetically in a metallic laboratory tubular reactor at 650 to 850°C and atmospheric pressure.Kinetic parameters were found to be a function of length of the alkylic side chain. A comparison with analogous parameters of n‐paraffins and the unsubstituted cyclohexane allowed the conclusion that CC‐scission in the alkylic chain is the initial reaction in pyrolysis of n‐alkylcyclohexanes followed by radical attacks to all CH‐bonds
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