Acrylic Terpolymer-Based Blends with Improved Properties
作者:
D. Feldman,
A. Blaga,
D. Banu,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1985)
卷期:
Volume 22,
issue 10
页码: 1385-1411
ISSN:0022-233X
年代: 1985
DOI:10.1080/00222338508063343
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Blending of acrylic terpolymer (AT) with vinyl acetate-vinyl chloride (VAc-VC) copolymer, polyvinyl alcohol (PVA) polymer, and polyvinyl acetate (PVAc) polymer, respectively, resulted in sealant compositions with improved properties and enhanced outdoor weathering resistance. The morphology of these blends was studied by SEM, energy-dispersive x-ray analysis (EDXA), and DSC. The blends are heterogeneous and consist of a continuous phase which is either pure or mixed AT and a particulate phase having the morphology of the added component. The particulate phase of AT and AT-(VAc-VC) copolymer blends contains mixed AT, whereas that of AT-PVA and AT-PVAc does not. The AT-based blends have generally improved mechanical properties (e.g., ultimate tensile strength, adhesive strength). The improvement in mechanical properties is particularly strong in mixtures of AT with (VAc-VC) copolymer, probably because the added component has greater specific interaction capabilities with AT than the polymers incorporated in the other blends. Whereas the unblended AT has very low outdoor durability, the AT-based blends display enhanced resistance to weathering, as evidenced by substantially higher ultimate tensile strength of weathered specimens than those of the controls (unweathered).
点击下载:
PDF (720KB)
返 回