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On the Structure of Oxirane Molecular Cation. Preliminary Communication

 

作者: Thomas Bally,   Stephan Nitsche,   Edwin Haselbach,  

 

期刊: Helvetica Chimica Acta  （WILEY Available online 1984）
卷期: Volume 67, issue 1  

页码: 86-90

 

ISSN:0018-019X

 

年代: 1984

 

DOI:10.1002/hlca.19840670111

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractA recent controversy on the interpretation of the ESR spectrum of ionized oxirane is clarified on the basis of the electronic absorption spectra of ionized tetramethyloxirane and 9,10‐octalineoxide. The results favour a ring‐opened structure for oxirane molecular cation, resulting from CC bond cleavage and being iso‐π‐electronic to all

 

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