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Cold Cathode Quadrupole Mass Spectrometer

 

作者: P. Blum,   F. L. Torney,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1967)
卷期: Volume 38, issue 10  

页码: 1404-1408

 

ISSN:0034-6748

 

年代: 1967

 

DOI:10.1063/1.1720549

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A magnetron cold cathode ion source (CCIS) has been developed for ultrahigh vacuum residual gas analysis. The purpose is to eliminate the spurious spectra produced by the conventional hot filament source and to obtain greater sensitivity. A commercial quadrupole mass analyzer was used to evaluate source performance and potential. Resolution equaled that obtained with a hot filament source, giving mass invariant peak separations, with 10% valleys, of 1.0 amu below 150 amu and 0.7 amu below 50 amu. Sensitivities exceeded those obtained with a hot filament source, operated at a 3 mA emission current, by factors of 1.5 to 4.6, depending on pressure and mass. The corresponding CCIS sensitivities, at 1‐amu peak separation, were 0.4 mA/Torr for mass 28 at 3×10−9Torr and 1.2mA/Torr for mass 40 at 1×10−7Torr. Experiments indicated a potential tenfold further sensitivity improvement if a quadrupole with a higher rf potential were used; by increasing quadrupole dimensions a still greater fraction of the source internal sensitivity, which is in the vicinity of 1 A/Torr, may be realized.

 

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