Magnetic susceptibilities of 14 iron‐vanadium alloys (to 26 at.% V) have been studied between their Curie temperatures and 1500°K. These alloys exhibit unusual paramagnetic behavior. Plots of the magnetic susceptibility vs vanadium concentration have a maximum which decreases with increasing temperatures. The curve of the paramagnetic Curie temperature vs at.% V also exhibits a maximum at about 10 at.% V. The paramagnetic moment per iron atom decreases gradually with the amount of vanadium in iron.