Evaluation of the interfacial tension between high molecular weight polycarbonate and PMMA resins with the imbedded fiber retraction technique
作者:
Craig J. Carriere,
Arie Cohen,
期刊:
Journal of Rheology
(AIP Available online 1991)
卷期:
Volume 35,
issue 2
页码: 205-212
ISSN:0148-6055
年代: 1991
DOI:10.1122/1.550212
出版商: The Society of Rheology
关键词: Interfacial tension, polymers;Polymer blends;Polymeric interfacial tensions;Surface tension, polymers;Polymer compatability;SURFACE TENSION;RESINS;POLYCARBONATES;PMMA;VISCOSITY;FLUID−FLUID INTERFACES;HIGH TEMPERATURE
数据来源: AIP
摘要:
The interfacial tension between molten, high molecular weight samples of polycarbonate and poly(methyl methacrylate) was measured using the imbedded fiber retraction (IFR) technique. A value of 1.44 ± 0.16 dyn/cm was measured at 240 °C. This value was obtained on commercial resins with zero‐shear bulk viscosities and at a temperature typically encountered in the processing of blends and/or composites. Refinements to the IFR method were implemented which reduced the experimentation time. Consequently, measurements of the interfacial tension can now be routinely obtained in several hours for materials with zero‐shear bulk viscosities on the order of 104Pa s.
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