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Asymmetric Induction in Free Radical Additions of Thiols to Olefins

 

作者: Masakuni Yoshihara,   Kenji Nozaki,   Hisashi Fujihara,   Toshihisa Maeshima,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1982）
卷期: Volume 18, issue 3  

页码: 411-419

 

ISSN:0022-233X

 

年代: 1982

 

DOI:10.1080/00222338208056510

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Asymmetric inductions have been achieved in the free radical additions of (1)l-menthyl mercaptoacetate to such prochiral olefins as crotonic acid, methyl crotonate, and a-methylstyrene (enantiofacedifferentiation), and (2) achiral thiols to g-menthyl and isobornyl crotonates (diastereoface differentiation).

 

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