FISCHER-TROPSCH CATALYSTS. ATTRITION OF CARBIDED IRON CATALYST IN THE SLURRY PHASE
作者:
Ram Srinivasan,
Liguang Xu,
RobertL Spicer,
FredL Tungate,
BurtronH. Davis,
期刊:
Fuel Science and Technology International
(Taylor Available online 1996)
卷期:
Volume 14,
issue 10
页码: 1337-1359
ISSN:0884-3759
年代: 1996
DOI:10.1080/08843759608947642
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Unsupported iron Fischer-Tropsch synthesis catalyst, formed to a spherical shape and calcined in air, were carbided at 270°C with CO for 24 hours. Following carbiding, the material retained the shape and size of the calcined metal oxide. During agitation by rolling of a slurry, the average particle diameter decreased by about 50% during 450 hours; the attrited material retained a spherical shape so that size reduction was not due primarily to particle fracture. The average particle size (1/d3) was approximately linearly related to the rolling time, and the particle size distribution was fitted by the Weibull Probability Function.
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