Stereochemistry of Displacement Reactions at Phosphorus Atoms
作者:
R. F. Hudson,
M. Green,
期刊:
Angewandte Chemie International Edition in English
(WILEY Available online 1963)
卷期:
Volume 2,
issue 1
页码: 11-20
ISSN:0570-0833
年代: 1963
DOI:10.1002/anie.196300111
出版商: Hüthig&Wepf Verlag
关键词: Displacement reactions;Stereochemistry
数据来源: WILEY
摘要:
AbstractRecent interest in the stereochemistry of displacement reactions involving second row elements has led to rapid advances in the preparation and resolution of asymmetric phosphorus compounds. The changes in optical activity accompanying substitution at an optically active phosphorus atom, the reactivity of cyclic phosphates, and the mechanism of intramolecular decomposition reactions involving a phosphorus centre are discussed in terms of the electronic structure of possible transition states.
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