Recent investigations have shown that unoriented phase I poly(vinylidene fluoride) films can be produced by pressure quenching. The poling field dependence of the pyroelectric coefficientPy, the piezoelectric coefficientsdp,d31ande31, and the dielectric response is investigated for poling fields up toEp= 2.75×106V/cm. These quantities exhibit a plateau region where the initial rapid increase with increasingEpdecreases. This behavior is similar to that observed for unoriented and biaxially oriented phase II poly(vinylidene fluoride) films. The effect of draw ratio ondpandPyfor draw ratios up to 6:1 is also examined.dpincreases from 6.5 to 19 pC/N as the draw ratio goes from 1:1 to 6:1 (at constantEp).Pyincreases from 1×10−9to 5×10−9C/cm2 K.