Complex Dielectric Constant of Liquid Crystal Materials Containing Ionic Impurities in Low Frequency Region
作者:
Atsushi Sawada,
Yuji Nakazono,
Kazuaki Tarumi,
Shohei Naemura,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 318,
issue 1
页码: 225-242
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808045386
出版商: Taylor & Francis Group
关键词: mobile ions;dielectric constant;dielectric loss factor;diffusion coefficient
数据来源: Taylor
摘要:
The dielectric properties of liquid crystal materials containing ionic impurities are analyzed in terms of space charge polarization. The theoretical expressions of the dielectric constant and the dielectric loss factor are derived by solving a diffusion equation for mobile ions under an AC field. Numerical calculations are performed using the theoretical expressions and the frequency dependent dielectric behaviors are simulated. The calculated curves for the dielectric constant and the dielectric loss factor exhibit a dielectric dispersion and a dielectric absorption respectively in a low frequency region, and successfully trace the observed curves obtained for liquid crystal materials 4-n-pentyl-4′-cyanobiphenyl (5CB) by means of curve fitting with the parameters of the diffusion coefficient and the density of mobile ions.
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