Influence of heterogeneous textures of polypropylene/ethylene–propylene–rubber blends on dynamic viscoelastic properties in molten state
作者:
Takao Nomura,
Takeyoski Nishio,
Shuichi Maeda,
Eiichi Kamei,
期刊:
Journal of Rheology
(AIP Available online 1995)
卷期:
Volume 39,
issue 4
页码: 803-803
ISSN:0148-6055
年代: 1995
DOI:10.1122/1.550675
出版商: The Society of Rheology
关键词: RUBBERS;POLYPROPYLENE;VISCOELASTICITY;STRESS−STRAIN RELATION;EMULSIONS;SOLUBILITY;ETHYLENE;MELTS;POLYMERS
数据来源: AIP
摘要:
Heterogeneous textures due to phase separation in molten polypropylene (PP)/ethylene–propylene–rubber (EPR) blends were investigated in relation to their dynamic viscoelastic properties. As characteristic to heterogeneous liquids, slow relaxation mechanisms due to the existence of such phases were found for dynamic moduli of PP/EPR blends. These moduli were analyzed by using the linear viscoelastic constitutive equation for an emulsion model developed for the concentrated emulsion and the blending equation for dissimilar polymer system. The results show that the matrix of PP/EPR blends is not pure PP but the mixture of PP and EPR. For the same blend composition, the EPR concentration in the matrix PP phase was larger for EPR containing more propylene units. For the blends having the same EPR, the EPR concentration in the matrix was larger for higher EPR content.
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