Supported Chromium Oxide Catalyst for Olefin Polymerization. V. Measurement of Catalytic Activity in an Integral Dynamic Reactor
作者:
G. Willaume,
A. Revillon,
R. Spitz,
A. Guyot,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1971)
卷期:
Volume 5,
issue 3
页码: 559-573
ISSN:0022-233X
年代: 1971
DOI:10.1080/00222337108061044
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
An integral dynamic reactor has been used for the continuous measurement of the instantaneous polymerization rate. With ethylene as monomer, the rate goes through a maximum after a few minutes, then levels off, and finally decreases owing to the blocking of the surface by the polymer. The catalytic activity may be calculated safely from the maximum instantaneous rate, after correction for the monomer consumption along the column of catalyst. As examples of application, it is shown that the catalytic activity goes through a maximum with either the chromium content at a fixed temperature of polymerization or with the temperature at a fixed chromium content.
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