Numerical Simulations of Aqueous Ozone Decomposition
作者:
K. Chelkowska,
D. Grasso,
I. Fábián,
G. Gordon,
期刊:
Ozone: Science & Engineering
(Taylor Available online 1992)
卷期:
Volume 14,
issue 1
页码: 33-49
ISSN:0191-9512
年代: 1992
DOI:10.1080/01919519208552316
出版商: Taylor & Francis Group
关键词: Ozone;Ozone Decomposition in Aqueous Solutions;Models for Aqueous Ozone Decomposition;Hydrogen Peroxide Effects;Carbonate Ion Effects;Ozonide Ion Radical;Kinetics of Ozone Decomposition;Mechanisms of Ozone;Decomposition
数据来源: Taylor
摘要:
The decomposition of ozone in basic aqueous solutions was simulated on the basis of two previously reported detailed mechanisms. According to the calculations, the mechanism given by Tomiyasu, Fukutomi and Gordon5is an appropriate model for the ozone decomposition, both in the presence and the absence of hydrogen peroxide and/or carbonate ion in basic solution. On the basis of this mechanism the main chain carrier is the ozonide ion radical.
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