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Intensity parameters for the Raman trace and anisotropic scattering of methyl iodide

 

作者: J. Santos,   J.M. Orza,  

 

期刊: Molecular Physics  (Taylor Available online 1990)
卷期: Volume 70, issue 4  

页码: 645-665

 

ISSN:0026-8976

 

年代: 1990

 

DOI:10.1080/00268979000102641

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The absolute Raman intensities of all fundamental bands of CH3I, CH2DI, CHD2I and CD3I, previously reported, are used to obtain the derivatives of the molecular polarizability with respect to the symmetry coordinates. Special attention is paid to anisotropic scattering, and the influence of data from the high-resolution spectra is discussed both from theoretical and practical points of view. The bond-polarizability model is used for interpreting the derived Raman intensity parameters ∂α/∂Si. While for trace scattering the results are consistent, we have found that the ratio between diagonal and non-diagonal components of ∂α/∂Siis not reproduced well by the model.

 

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