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Nuclera Quadrupolar Relaxation in Liquid Metals

 

作者: T. Gaskell,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1978)
卷期: Volume 8, issue 1  

页码: 23-35

 

ISSN:0031-9104

 

年代: 1978

 

DOI:10.1080/00319107808084739

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

It is well known that the theory of the quadrupolar relaxation rate, R1Q, may be expressed in liquids in terms of a time-dependent correlation function which describes the relative motion of the atoms. A new, intuitive approach to the correlation problem is developed, emphasising the effect of the close-range atomic encounters on the relaxation rate and an explicit T−½temperature dependence of the contribution to R1Qfrom such processes is demonstrated. Other contributions are discussed, but since the experimental measurements of the quadrupolar relaxation rate in liquid metals indicate a close proportionality to T−½it is suggested that the short-range collisions play the dominant role in determining the relaxation rate.

 

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