Nuclera Quadrupolar Relaxation in Liquid Metals
作者:
T. Gaskell,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1978)
卷期:
Volume 8,
issue 1
页码: 23-35
ISSN:0031-9104
年代: 1978
DOI:10.1080/00319107808084739
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
It is well known that the theory of the quadrupolar relaxation rate, R1Q, may be expressed in liquids in terms of a time-dependent correlation function which describes the relative motion of the atoms. A new, intuitive approach to the correlation problem is developed, emphasising the effect of the close-range atomic encounters on the relaxation rate and an explicit T−½temperature dependence of the contribution to R1Qfrom such processes is demonstrated. Other contributions are discussed, but since the experimental measurements of the quadrupolar relaxation rate in liquid metals indicate a close proportionality to T−½it is suggested that the short-range collisions play the dominant role in determining the relaxation rate.
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