Magnetic Interactions in the Crystals of α- and β-Phases of 2-Hydro Nitronyl Nitroxide and Related Compounds
作者:
Yuko Hosokoshi,
Masafumi Tamura,
Kiyokazu Nozawa,
Satoshi Suzuki,
Hiroshi Sawa,
Reizo Kato,
Minoru Kinoshita,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 271,
issue 1
页码: 115-122
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508034044
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Magnetic properties and crystal structures of α-and β-2-hydro nitronyl nitroxide radicals (2-hydro-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide) were investigated. Exchange couplings in both phases were estimated from the parainagnetic susceptibility (1.8-300 K) and magnetization (up to 400 kOc) measurements. Assignment of the couplings to molecular packings has been carried out. Close spacing between the ONCNO moietics yields various magnitude of exchange couplings from 0 toca.-30 K. In α-phase crystal, short contacts between the central carbon atoms with negative spin density and the NO groups with positive spin density were observed. However, this packing is assigned to an antiferromagnetic exchange coupling,J/kB= −11 K (ℋ= −2JS1.S2). This case suggests that care must be taken when we refer to McConnell's proposal.
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