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Thermodynamic tabulations for selected phases in the system CaO‐Al2O3‐ SiO2‐H2at 101.325 kPa (1 atm) between 273.15 and 1800 K

 

作者: John L. Haas Jr.,   Glipin R. Robinson Jr.,   Bruce S. Hemingway,  

 

期刊: Journal of Physical & Chemical Reference Data  (AIP Available online 1981)
卷期: Volume 10, issue 3  

页码: 575-670

 

ISSN:0047-2689

 

年代: 1981

 

DOI:10.1063/1.555645

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The standard thermodynamic properties of phases in the lime‐alumina‐silica‐ water system between 273.15 and 1800 K at 101.325 kPa (1 atm) were evalated from published experimental data. Phases included in the compilation are boehmite, diaspore, gibbsite, kaolinite, dickite, halloysite, andalusite, kyanite, sillimanite, Ca‐Al cliniopyroxene, anorthite, gehlenite, grossular, prehnite, zoisite, margarite, wollastonite, cyclowollastonite ( = pseudowollastonite), larnite, Ca olivine, hatrurite, and rankinite. The properties include heat capacity, entropy, relative enthalpy, and the Gibbs energy function of the phases and the enthalpies, Gibbs energies, and equilibrium constants for formation both from the elements and the oxides. Tabulated values are given at 50 K intervals with the 2‐sigma confidence limit at 250 K intervals. Summaries for each phase give the temperature‐ dependent functions for heat capacity, entropy, and relative enthalpy and the experimental data used in the final evaluation.

 

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