The kinetic glass transition of theZr46.75Ti8.25Cu7.5Ni10Be27.5bulk metallic glass former-supercooled liquids on a long time scale
作者:
R. Busch,
W. L. Johnson,
期刊:
Applied Physics Letters
(AIP Available online 1998)
卷期:
Volume 72,
issue 21
页码: 2695-2697
ISSN:0003-6951
年代: 1998
DOI:10.1063/1.121102
出版商: AIP
数据来源: AIP
摘要:
Viscosity and enthalpy relaxation from the amorphous state into the supercooled liquid state was investigated in the bulk metallic glass formingZr46.75Ti8.25Cu7.5Ni10Be27.5alloy below the calorimetric glass transition. At different temperatures, the viscosities relax into states that obey the same Vogel–Fulcher–Tammann relation as the data obtained at higher temperatures in the supercooled liquid. Enthalpy recovery experiments after relaxation in the same temperature range show that the enthalpy of the material reaches values that also corresponds to the supercooled liquid state. The glass relaxes into a metastable supercooled liquid state, if it is observed on a long time scale. Equilibration is possible far below the calorimetric glass transition and very likely even below the isentropic temperature. ©1998 American Institute of Physics.
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