CONFORMATIONAL EQUILIBRIA IN DIETHYL KETONE
作者:
R. Norman Jones,
K. Noack,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1961)
卷期:
Volume 39,
issue 11
页码: 2214-2224
ISSN:0008-4042
年代: 1961
DOI:10.1139/v61-293
出版商: NRC Research Press
数据来源: NRC
摘要:
A variable-thickness, variable-temperature absorption cell, modified from the design of Holden, Taylor, and Johnston, has been used to compare the infrared spectrum of diethyl ketone at −75° and +25 °C. The Raman spectrum of diethyl ketone has also been measured at +6°, +25°, and +85 °C, and the proton magnetic resonance spectrum over the range −61° to 104 °C.Both the infrared and Raman spectra exhibit pronounced temperature sensitivity, which is attributed to the presence of at least two conformational isomers in the liquid phase. Possible structures for these isomers are considered. Small but significant chemical shifts are noted in the proton magnetic resonance spectrum.
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