Nuclear spin relaxation in electrolyte solutions.
作者:
M.St.J. Arnold,
K.J. Packer,
期刊:
Molecular Physics
(Taylor Available online 1968)
卷期:
Volume 14,
issue 3
页码: 241-248
ISSN:0026-8976
年代: 1968
DOI:10.1080/00268976800100271
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A general discussion is given of the problems of assigning changes in nuclear spin relaxation rates, brought about by changes in system composition, temperature, etc., to changes in correlation times and/or nucleus-lattice coupling energies. In particular the usually assumed proportionality of correlation time and viscosity is examined in detail for aqueous electrolyte solutions. It is concluded that for ions which have a marked effect on the ‘structural equilibrium’ of the water, the correlation time—viscosity proportionality is unlikely to exist. It is suggested that in favourable cases individual particle self-diffusion coefficients are likely to be related in a simple way to correlation times. This is supported by available results for aqueous potassium iodide solution.
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