Efficiency of the Pruitt-Baggett Catalyst in the Stereoregular Polymerization of Propylene Oxide
作者:
N. Clolak,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1996)
卷期:
Volume 35,
issue 2
页码: 317-325
ISSN:0360-2559
年代: 1996
DOI:10.1080/03602559608000586
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Partially stereoregular poly(propylene oxide) (PPO), samples synthesized by the Pruitt-Baggett Catalyst (PBC) were fractionated at 25CEC and 50°C from acetone by adding small portions of water. At 25°C mainly solid-liquid phase separations took place. On the other hand, at 50°C, liquid-liquid phase separations were observed. Thus, it was possible to fractionate PPO on the basis of molecular weight. From the molecular weight measurements, it was concluded that 1 molecule of high PPO was formed for less than 10 Fe atoms.
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