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THEORY OF POLARIZED FLUORESCENCE FROM MOLECULAR PAIRS: FÖRSTER TRANSFER AT LARGE ELECTRONIC COUPLING

 

作者: Robert S. Knox,   Demet Gülen,  

 

期刊: Photochemistry and Photobiology  (WILEY Available online 1993)
卷期: Volume 57, issue 1  

页码: 40-43

 

ISSN:0031-8655

 

年代: 1993

 

DOI:10.1111/j.1751-1097.1993.tb02252.x

 

出版商: Blackwell Publishing Ltd

 

数据来源: WILEY

 

摘要:

AbstractPolarization properties of the fluorescence from a pair of identical molecules coupled electronically are examined on the basis of a stochastic Liouville equation formalism developed in 1979 by Rahman, Knox and Kenkre. The time development of polarization is calculated for random ensembles of rigid molecule pairs under initial conditions that represent either selective excitation or broad‐band coherent excitation. We hold that the applicability of the Forster mechanism is not limited to cases of weak coupling, and we indicate the rationale and a method for observing it in cases involving large interaction between transition dipole

 

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