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A Variation in Acid-Catalyzed Isomerization of Abietadienoic Acids

 

作者: DuaneF. Zinkel,  

 

期刊: Journal of Wood Chemistry and Technology  (Taylor Available online 1991)
卷期: Volume 11, issue 4  

页码: 439-446

 

ISSN:0277-3813

 

年代: 1991

 

DOI:10.1080/02773819108051085

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Heating the individual common abietadienoic acid methyl esters withp-toluene sulfonic acid in chloroform led to the formation of methyl abietadienoates other than the equilibrium mixture of methyl abietate, palustrate, and neoabietate that is usually formed by acid-catalyzed isomerization. Of these other methyl abietadienoates, the three principal constituents comprised 10%, 4% and 2% of the monomers; these compounds were isolated and identified as methyl 13β-abieta-7,9(11)-dien-18-oate, methyl 7,9(11)-abietadien-18-oate, and methyl 8,12-abietadien-18-oate, respectively.

 

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