Synthesis and Some Properties of Some Sulfonium Polyelectrolytes: Polymers and Copolymers Derived from Methylthioethyl Acrylate
作者:
F.E. Bailey,
E.M. La Combe,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1970)
卷期:
Volume 4,
issue 6
页码: 1293-1300
ISSN:0022-233X
年代: 1970
DOI:10.1080/00222337008081730
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Methylthioethyl acrylate, prepared by ester exchange from methylthioethanol and methyl acrylate, behaves in copolymerization like a typical acrylate ester such as butyl acrylate. This monomer can be alkylated to yield corresponding sulfonium monomers. With dimethyl sulfate, (2-acryloxyethyl) dimenthylsulfonium methyl sulfate is obtained. This latter monomer has a predictable lower relative copolymerization rate with alkyl acrylates than methylthioethyl acrylate. Water-soluble sulfonium polymers are polymeric cations and can act effectively as flocculants.
点击下载:
PDF (231KB)
返 回