Elastomers with Polysulfidic Cross Links Viewed as Bimodal Networks
作者:
M.A. Sharat,
J.E. Mark,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1991)
卷期:
Volume 28,
issue sup1
页码: 67-73
ISSN:0022-233X
年代: 1991
DOI:10.1080/00222339108054385
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Elastomers cured with sulfur frequently have improved mechanical properties when the curing conditions are chosen so as to give cross links that consist of chains of Sulfur atoms. If such polysulfidic cross links themselves act as elastomeric network chains, then a bimodal network is produced, albeit inadvertently. Interpretation of its properties requires, accordingly, changes in the description of the network structure, most importantly the replacement of one tetrafunctional cross link by two trifunctional ones separated by a new network chain. Illustrative calculations can be used to elucidate the deformation of such networks in terms of the molecular models much used to characterize simpler, unimodal elastomers. More detailed calculations give results in good agreement with experiment.
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