Electron spin resonance spectra of irradiated monofluoracetamide
作者:
R.J. Cook,
J.R. Rowlands,
D.H. Whiffen,
期刊:
Molecular Physics
(Taylor Available online 1964)
卷期:
Volume 7,
issue 1
页码: 31-43
ISSN:0026-8976
年代: 1964
DOI:10.1080/00268976300100791
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The radical trapped in x-irradiated monofluoracetamide is shown to be CHF CONH2by electron spin resonance studies. The principal values of the hydrogen hyperfine coupling are -96, -63 and -31 Mc/s and of the fluorine coupling are +530, -11 and -45 Mc/s. The relative signs of the principal couplings were established, using a spectrometer operating at 35 000 Mc/s which is briefly described. The differences in spectra between measurements at 9000 Mc/s and at 35 000 Mc/s are indicated. Finally the couplings are interpreted and shown to be consistent with Hückel parameters for fluorine with (αF-αC) = 2·4βC-F.
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