KINETIC ASPECTS OF THE ION EXCHANGE EXTRACTION OF GOLD, SILVER, AND BASE METAL CYANO COMPLEXES
作者:
P.A. Riveros,
W. Charles Cooper,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1988)
卷期:
Volume 6,
issue 3
页码: 479-503
ISSN:0736-6299
年代: 1988
DOI:10.1080/07366298808917951
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The simultaneous ion exchange extraction of selected pairs of noble and base metal cyano complexes was studied. In most cases It was found that equilibrium Is attained only after a period of several hours during which time the resin composition undergoes marked variations. As a rule, the loading of noble metals passes through a maximum value while the loading of base metals Increases steadily as equilibrium Is approached. Kinetic parameters, obtained by applying mathematical models to the experimental data, indicated that there are significant differences in dlffusivity among the various metal cyano complexes in both the Nernst diffusion layer and in the resin matrix. These differences assist in understanding the experimental observations.
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