Kinetic studies of α‐olefin polymerization
作者:
G. Natta,
期刊:
Journal of Polymer Science
(WILEY Available online 1959)
卷期:
Volume 34,
issue 127
页码: 21-48
ISSN:0022-3832
年代: 1959
DOI:10.1002/pol.1959.1203412703
出版商: Interscience Publishers, Inc.
数据来源: WILEY
摘要:
AbstractThe kinetics of chain growth and chain transfer processes in the stereospecific polymerization of propylene, using catalytic systems such as TiCl3Al(C2H5)3and TiCl3AlCl(C2H5)2, has been examined. The number of active centers present on the catalyst surface has been determined radiochemically by kinetic and adsorption measurements, using aluminum labeled with C14. The mean life of macromolecules was determined by radiochemical determination of terminal groups, and the relationships between intrinsic viscosity and number‐average molecular weight were found. Kinetic research into ethylene‐propylene copolymerization enableld us to determine the different reactivity ratios of t
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