Surface Phenomena in Microconfined Liquid Crystals: From Cylindrical Cavities to Polymer Networks
作者:
S. Zumer,
G.P. Crawford,
J.W. Doane,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 261,
issue 1
页码: 577-592
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508033499
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Confining effects of pre-filled porous matrices and anisotropic polymer networks formed during the polymerization of a small amount of prepolymer components in nematic liquid crystal matrices are studied. The pretransitional phenomena above the bulk nematic-isotropic phase transition temperature is modeled to determine the order parameter of the liquid crystal molecules at the surface of a submicrometer cylindrical cavity from magnetic resonance experiments, and to determine the order parameter of the polymer network formed in an anisotropic liquid crystal environment from birefringence measurements. From this model, we estimate the size of the internal surface of the polymer network.
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