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Thermodynamic Properties of Dioxygen Difluoride (O2F2) and Dioxygen Fluoride (O2F)

 

作者: John L. Lyman,  

 

期刊: Journal of Physical & Chemical Reference Data  (AIP Available online 1989)
卷期: Volume 18, issue 2  

页码: 799-807

 

ISSN:0047-2689

 

年代: 1989

 

DOI:10.1063/1.555830

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Recent spectroscopic and chemical kinetic studies have provided sufficient data for construction of reliable thermodynamic tables for both dioxygen difluoride (O2F2; Chemical Abstracts Registry Number, 7783‐44‐0) and dioxygen fluoride (O2F; Chemical Abstracts Registry Number, 15499‐23‐7). This paper contains those tables for these species in both SI units (0.1 MPa standard state) and cal K mol units (1.0 atm standard state). The experimental basis includes three recent assignments of the fundamental vibrational frequencies for O2F2, a new set of rotational constants for O2F, an enthalpy change for dissociation of O2F, and an updated standard enthalpy of formation for O2F2.

 

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