THE PHOTOLYSIS OF BIACETYL
作者:
P. Ausloos,
E. W. R. Steacie,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1955)
卷期:
Volume 33,
issue 1
页码: 39-46
ISSN:0008-4042
年代: 1955
DOI:10.1139/v55-007
出版商: NRC Research Press
数据来源: NRC
摘要:
The photolysis of biacetyl has been reinvestigated. The results are, in general, in excellent agreement with those of Blacet and Bell. Curvature occurs at low temperatures in the Arrhenius plot of[Biacetyl], and this is attributed to wall reactions, and to the disproportionation reactionAzomethane–biacetyl mixtures have been photolyzed to give further information on these points. An activation energy of 8.5 kcal. has been found for the reaction of methyl radicals with biacetyl.
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