A canal surface viscometer for the in‐plane steady shear viscosity of monolayers at the air/water interface
作者:
Mark Sacchetti,
Hyuk Yu,
George Zografi,
期刊:
Review of Scientific Instruments
(AIP Available online 1993)
卷期:
Volume 64,
issue 7
页码: 1941-1946
ISSN:0034-6748
年代: 1993
DOI:10.1063/1.1143980
出版商: AIP
数据来源: AIP
摘要:
A canal surface viscometer has been designed and constructed to measure the in‐plane steady shear viscosity (&eegr;s) of monolayers at the air/water interface. The technique involves forcing a monolayer to flow through a canal to another monolayer under a constant surface pressure gradient and measuring the area flow rate. The instrument incorporates a feedback electronic system to maintain the surface pressure on each side of the canal to about 0.1 dyn/cm during monolayer flow. The canal design is modified from that of an earlier design in the literature to eliminate artifacts that give rise to systematic variabilities as reported. Specifically, it is demonstrated that the glass‐paraffin canal design used in the past produces ill reproducible results in contrast to an all Teflon canal, which gives rise to consistently reproducible surface viscosity data. A comparison is made between &eegr;svalues obtained from the canal viscometer and the knife‐edge ring surface viscometer, another technique reported in the literature. The comparison reveals the importance of controlling key experimental variables which can have an order‐of‐magnitude effect on the surface viscosity data.
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