On the Michaelis–Menten behavior of pyridinium chloro chromate oxidations: Oxidation of dimethyl, dipropyl, and diphenyl sulfide in chlorobenzene–nitrobenzene mixtures
作者:
G. P. Panigrahi,
D. D. Mahapatro,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1981)
卷期:
Volume 13,
issue 1
页码: 85-96
ISSN:0538-8066
年代: 1981
DOI:10.1002/kin.550130108
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThe kinetics of oxidation of dimethyl, dipropyl, and diphenyl sulfides by pyridinium chloro chromate in chlorobenzene–nitrobenzene mixtures are reported. The rate data show Michaelis–Menten behavior. The oxidation process is catalyzed by the organic acids like dichloro and trichloro acetic acids. The rate‐determining step appears to be a unimolecular decomposition of a complex of the reac
点击下载:
PDF
(433KB)
返 回