Theory of collisional energy transfer of highly excited molecules
作者:
RobertG. Gilbert,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1991)
卷期:
Volume 10,
issue 3
页码: 319-347
ISSN:0144-235X
年代: 1991
DOI:10.1080/01442359109353261
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The method of obtaining collisional energy transfer data for collisions between a highly excited polyatomic and a bath gas from classical trajectories is discussed. The technique yields the mean(-square) energy transferred per collision from a comparatively small (≊500) number of trajectories. Results compare favourably, qualitatively and quantitatively, with experiment for all except the lightest bath gases (where the interaction potential is uncertain). Simple analytical models are also examined. These yield methods of obtaining energy transfer data of practical use in predicting and interpreting falloff data for unimolecular and recombination reactions. It is shown that quantum effects are unimportant for such systems.
点击下载:
PDF (1908KB)
返 回