Multiphase Polymer Processing: Controlled‐Ingredient‐Distribution Mixing and Its Effect on the Covulcanization of Elastomer Blend Compounds
作者:
Biing‐Lin Lee,
期刊:
Journal of Rheology
(AIP Available online 1984)
卷期:
Volume 28,
issue 4
页码: 307-324
ISSN:0148-6055
年代: 1984
DOI:10.1122/1.549753
出版商: The Society of Rheology
数据来源: AIP
摘要:
Controlled‐ingredient‐distribution mixing technology has been exploited in a study of the covulcanization of an SBR‐NBR blend. The technique of differential solvent (or oil) swelling is applied to indicate the existence or absence of interfacial bonds between the SBR and NBR rubber phases. The analysis of swelling based on the fact that (1) NBR is hardly swollen in ASTM #2 oil, while SBR is highly swollen; and (2) the swelling restriction of the SBR‐rich compounds due to the presence of NBR is analogous to the swelling restriction of elastomer networks containing reinforcing fillers. The results on oil swelling, tensile properties, tear strength, and also flex crack growth resistance all indicate that interfacial bonds between the NBR and SBR phases can be achieved by appropriately controlling the distribution of black and other ingredients in the individual rubber phases.
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