A New Reptation Model for the Rheological Properties of Concentrated Polymer Solutions and Melts
作者:
Bernard J. Geurts,
Robert J. J. Jongschaap,
期刊:
Journal of Rheology
(AIP Available online 1988)
卷期:
Volume 32,
issue 4
页码: 353-365
ISSN:0148-6055
年代: 1988
DOI:10.1122/1.549969
出版商: The Society of Rheology
数据来源: AIP
摘要:
The constitutive equation for the “elastic flexible reptating rope” model is derived. In this model the macromolecule is represented by a continuous flexible elastic rope, confined in a tube along its contour and performing a reptation motion. The analytical expressions for the relative extension and the one‐ and two‐segment distribution functions are derived. This enables the determination of the explicit form of the constitutive equation. Due to the elasticity of the rope, fast internal relaxation modes appear in the theory as well as long reptation times. It is expected that fast deformation processes can therefore be described accurately by this constitutive equation.
点击下载:
PDF
(592KB)
返 回