Dipole–Dipole Interaction of Substitutional Impurity Molecules in Crystals
作者:
N. E. Kamenogradskii,
Yu. V. Konobeev,
期刊:
physica status solidi (b)
(WILEY Available online 1970)
卷期:
Volume 37,
issue 1
页码: 29-37
ISSN:0370-1972
年代: 1970
DOI:10.1002/pssb.19700370103
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractA theory is given of effective dipole—dipole interactions between two identical substitutional guest molecules at large intermolecular distance. An interaction theory for interstitial impurity molecules was developed in [3]. A two‐level scheme for the guest and host molecules is assumed. Local field corrections are discussed. It is shown that the dipole—dipole interaction of the guest molecules in a crystal is the interaction of the effective dipole moments. The values of such effective dipole moments differ from their values in vacuum by a factor which is expressed both by the dielectric constant at the impurity transition frequency and the microscopic characteristics of the m
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