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XXVI.—Description of the lapis lazuli found in large quantities in the Cordilleras of the Andes

 

作者: F. Field,  

 

期刊: Quarterly Journal of the Chemical Society of London  (RSC Available online 1852)
卷期: Volume 4, issue 4  

页码: 331-332

 

ISSN:1743-6893

 

年代: 1852

 

DOI:10.1039/QJ8520400331

 

出版商: RSC

 

数据来源: RSC

 

摘要:

THE QUARTERLY JOURNAL OF TEE CHEMICAL SOCIETY. XXVI.-Descr&tion of the Lapis Lazuli found in large quantities in the Cordilleras of the Andes. BY F. FIELD,F.C.S. The discovery of immense masses of a bright blue rock in the Cordilleras led a miner to suppose he had discovered a vein of the blue carbonate of copper. On analyzing a specimen I found it to be perfectly destitute of that metal and to be in fact a true lapis lazuli interspersed with small veins of pure carbonate of lime. Heated by itself it loses colour but regains its primitive appearance on cooling; with nitre on the application of the blow- pipe flame it becomes highly incandescent and of a most beautiful green. It dissolves in borax with lively effervescence into a pure colourless glass becoming slightly opalescent on cooling.On the addition of nitric acid there is a brisk evolution of carbonic acid- the mineral becomes perfectly colourless and presents a solid mass of gelatinous silica. The following is its composition in 100 parts. The analysis offered no dificulties Silica 37.60 Alumina . 11.21 Sulphur . 1.65 Iron . 0.08 Magnesia . 0.36 Soda . 9.66 Carbonic acid 15-05 Lime . 24.10 - 99-71 VOL. 1V.-NO. XVL. AA 332 MR FIELD ON THE ANALYSIS OF A MINERAL This probably is not exactly the proper expression of its constitu- tion the sulphur no doubt being in combination with a portion of the sodium from the soda as well as with iron. That the sulphur exists as such and not in the state of sulphuric acid is evident by the addition of acetic acid which causes a strong disengagement of sulphuretted hydrogen and in the residue no trace of sulphur can be detected by solution and addition of a salt of baryta. I believe the colour of the stone is usually attributed to minute portions of sulphide of iron and sodium. Gmelin however in an analysis of lapis lazuli places all the sulphur as sulphuric acid. (See Chapman’s Mineralogy p. 81.)

 

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