Synthesis and Properties of Polyamides of 2,2′-[Isopropylidenebis-(p-phenyleneoxy)] diacetic Acid
作者:
K.J. Scariah,
V.N. Krishnamurthy,
K.V. C. Rao,
M. Srinivasan,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1985)
卷期:
Volume 22,
issue 12
页码: 1753-1772
ISSN:0022-233X
年代: 1985
DOI:10.1080/00222338508063369
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A group of six semiaromatic polyamides of 2,2′-[isopropylidenebis-(p-phenyleneoxy)]diacetic acid (Bisacid A2) were synthesized by low-temperature solution polycondensation techniques. Six different diamines were condensed independently with Bisacid A2chloride in a mixture of N-methylpyrrolidone (NMP and hexamethylhosphoramide (HMPA). The polymers were obtained in 82–95% yield and possessed inherent viscosities in the range from 0.32 to 0.63 dL/g. The polyamides were characterized by IR and 'H-NMR spectra. The molecular weight and molecular weight distribution of the polyamides were determined by gel-permeation chromatography. The thermal stability, thermal degradation kinetics, crystallinity, density, and solubility were also determined. A model diamide (MDA) was synthesized from aniline and Bisacid A2chloride to confirm the formation of polyamides from diamines.
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