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Exciton States and Band Structure in CdS and CdSe

 

作者: J. J. Hopfield,  

 

期刊: Journal of Applied Physics  (AIP Available online 1961)
卷期: Volume 32, issue 10  

页码: 2277-2281

 

ISSN:0021-8979

 

年代: 1961

 

DOI:10.1063/1.1777059

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The theoretical effects of a finite slope condition band crossing on the direct exciton energy levels of wurtzite compounds is investigated. The lack of an experimental confirmation of these effects places an upper limit of about 10−10ev‐cm on the slope of the conduction band atk= 0 in CdS, and a slightly larger limit in CdSe. Theoretical estimates of these slopes are also calculated. Another possible method of observing the magnetic effects due to the nonzero wave vector of the excitons is noted. The striking increase of the exciton oscillator strength in CdSe in a magnetic field is attributed to the magnetic compression of the excitons. A brief comparison of experimental energy band parameters for CdS and CdSe is given.

 

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