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Evaluation of end effects in capillary rheometers for solutions of flexible polymers

 

作者: Lourdes de Vargas,   José Pérez‐González,   Javier de J. Romero‐Barenque,  

 

期刊: Journal of Rheology  (AIP Available online 1995)
卷期: Volume 39, issue 1  

页码: 125-137

 

ISSN:0148-6055

 

年代: 1995

 

DOI:10.1122/1.550694

 

出版商: The Society of Rheology

 

关键词: POLYMERS;SOLUTIONS;END EFFECTS;MEASURING INSTRUMENTS;CAPILLARY FLOW;POLYETHYLENES;ACRYLAMIDE;CONFORMATIONAL CHANGES;SLIP FLOW;MACROMOLECULES;SHEAR FLOW;SLIP FLOW

 

数据来源: AIP

 

摘要:

Flow experiments with a capillary rheometer using 0.3% polyacrylamide and 0.75% polyox aqueous solutions were performed to study flow development and end effects generated by polymer solutions of flexible macromolecules. SeveralL/Dcapillary ratios were employed, and a method proposed recently was used to evaluate the corrections due to end effects. The corrections obtained are of the same order of magnitude than those obtained using the Bagley method, but the Bagley corrections have much larger uncertainties. The recently proposed method is superior to the Bagley method when accurate end effects are required, as for correlations with elasticity or to evaluate numerical predictions for the flow behavior of these fluids.

 

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