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Rate of Recrystallization of Polyethylene Single Crystals

 

作者: W. O. Statton,  

 

期刊: Journal of Applied Physics  (AIP Available online 1961)
卷期: Volume 32, issue 11  

页码: 2332-2334

 

ISSN:0021-8979

 

年代: 1961

 

DOI:10.1063/1.1777068

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Platelet crystals of linear polyethylene recrystallize extremely rapidly when immersed in a bath of a hot liquid such as ethylene glycol, glycerine, or Woods metal. This recrystallization rate is much faster and to greater extent than when the heating medium is air. For example, heating in the liquids at 127°C causes the length of the chains between folds to increase 50% in 1 sec; the ultimate increase of 200% occurs in about 10 sec. No definite explanation is presently apparent for this much faster rate and greater extent in liquids. No evidence is found for reversibility when annealed crystals are reheated at a lower temperature.

 

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