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Reactivity of octachlorocyclotetraphosphazene towards alkyllithium reagents; formation of bi(cyclotetraphosphazenes)

 

作者: Herman Winter,   Johan C. van de Grampel,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1984）
卷期: Volume 103, issue 7‐8  

页码: 241-242

 

ISSN:0165-0513

 

年代: 1984

 

DOI:10.1002/recl.19841030705

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractReactions of octachlorocyclotetraphosphazene (NPCl2)4with methyl lithium and isopropylalcohol or alkyl iodides afford hydrido‐phosphazenes and bi(cyclotetraphosphazenes). A reaction mechanism, based on an initial metal‐halogen exchange process, is propo

 

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