Homogeneous Photoinduced Graft Copolymerization of 4-Vinyl Pyridine onto Ethyl Cellulose. 1. Influence of Biacetal and Acetonaphthone Derivatives
作者:
E.M. Abdel-Bary,
E.A. Abdel-Razik,
A.A. Sarhan,
N.M. Abdel-Salam,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1996)
卷期:
Volume 35,
issue 6
页码: 947-957
ISSN:0360-2559
年代: 1996
DOI:10.1080/03602559608000609
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Homogeneous photoinduced graft copolymerization of 4-vinyl pyridine (4-VP) onto ethyl cellulose (EC) in the presence of three photosensitizers such as 1-acetonaphthone (1-An), 2-acetonaph-thone (2-An), and biacetal (Bi) in benzene solution was extensively investigated. Ultraviolet (UV) irradiation in the range 310 to 460 nm was used. The U V spectra of the mentioned photosensitizers showed n-π*transitions. Grafting parameters such as grafting percentage (GP) and grafting efficiency (GE) were determined as functions of the irradiation time and the concentrations of monomer, substrate, and initiator. The IR spectrum of the EC-g-4-VP copolymer shows the appearance of new peaks between 1600 and 1690 cm-1indicating the presence of poly-4-vinyl pyridine (p-4-VP) grafted chains. The rate of copolymerization of 4-VP onto EC in the presence of 1-An, 2-An, and Bi was determined as 0.98% min-1, 0.88% min-1and 0.042% min-1, respectively.
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