Chemical potential of hard-sphere fluids by Monte Carlo methods
作者:
D.J. Adams,
期刊:
Molecular Physics
(Taylor Available online 1974)
卷期:
Volume 28,
issue 5
页码: 1241-1252
ISSN:0026-8976
年代: 1974
DOI:10.1080/00268977400102551
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The ‘potential distribution’ expressions derived by Widom for the pressure and chemical potential of a fluid are developed for the special case of a hard-sphere fluid. The exact equations produced are closely related to those used in Scaled Particle Theory. They have been used to determine the chemical potential of hard-sphere fluids over the reduced density range 0·1 ⩽σ3ρ⩽ 0·8 by means of Monte Carlo sampling. The chemical potential so obtained is in excellent agreement with that found by integrating over pressure as a function of volume. It is found, however, that the chemical potential is considerably more dependent on the sample size than the pressure.
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