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TrijuginsAandB, tetranortriterpenoids with a novel rearranged carbon skeleton fromHeyneatrijuga(Meliaceae)

 

作者: Kozhiparambil K. Purushothaman,   Mathuram Venkatanarasimhan,   Ayyappath Sarada,   Joseph D. Connolly,   David S. Rycroft,  

 

期刊: Canadian Journal of Chemistry  (NRC Available online 1987)
卷期: Volume 65, issue 1  

页码: 35-37

 

ISSN:0008-4042

 

年代: 1987

 

DOI:10.1139/v87-008

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

Two new tetranortriterpenoids, trijuginsA(1) andB(3), isolated from the leaves ofHeyneatrijuga(Meliaceae), have been shown to be derivatives of methyl angolensate but with a novel carbon skeleton having a contracted ring C. The structures were assigned on the basis of detailed1H and13C nuclear magnetic resonance spectroscopic examination including 2D long-range δC/δHcorrelation and homonuclear1H nuclear Overhauser effect difference experiments.

 

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